Behaviour and Microstructural Characteristics of Lime-GGBS-Treated Kaolin Clay Contaminated with Gypsum
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Jeremiah J. Jeremiah, Samuel J. Abbey, Colin A. Booth, Anil Kashyap
A road can fail not because its soil is too weak, but because the repair material makes it swell. This study finds a different mixture that strengthens the ground while sharply reducing that dangerous expansion.
In this experimental study, the physico-mechanical and microstructural properties of sulphate-bearing clays have been investigated. Sulphate bearing soils constituted by mixing kaolin and gypsum at 0%, 15%, 25%, and 35% gypsum contents were treated with 12% ordinary Portland cement (OPC) and 4%Lime (L) and 8% ground granulated blast furnace slag (GGBS) and subjected to compaction, swell, unconfined compressive strength (UCS), California bearing ratio (CBR), and scanning electron microscopy (SEM) and energy dispersive spectrometry (EDX) analyses. The results of the study showed that the use of L-GGBS improved the soaked CBRs of the treated samples by over 43% when compared to OPC-treated samples after 7-days curing. A reduction in water absorption by 82% was also observed with L-GGBS treatment after 28-days curing. The UCS results also showed better performance with L-GGBS treatment exceeding 856% at 28 days. The effect of increased cementitious product with increasing gypsum content was negated by simultaneous and rapid growth of ettringite minerals which reduced the strength and increased swelling of OPC treated samples up to 18.92%, exceeding allowable limits of 2.5% as specified in Highway Agency Advice Note HA 74/07. The L-GGBS treated gypseous soil samples meet the strength requirement for stabilised sub-base (CS) and stabilised road-bases (CB1 and CB2) as described in TRL ORN31. Hence, the use of L-GGBS combination was found to be effective in ameliorating sulphate-induced expansion and therefore encouraged in the stabilisation of subgrade and road-base materials with high sulphate contents.
Transcript
A road can fail not because its soil is too weak, but because the repair material makes it swell. This study finds a different mixture that strengthens the ground while sharply reducing that dangerous expansion. Roads and other structures depend on knowing how treated soil will behave.
The safety and durability of facilities built on engineered earth materials depend directly on correctly modelling that behaviour. But sulphate-rich soil creates a difficult trap: treating it with cement or lime has produced expansion and drying cracks, while sulphate can also leave the treated ground weaker, more permeable, and unstable in volume.
The gap was not simply whether the soil could be treated. There was insufficient information about how a lime-and-furnace-slag mixture would behave in highly gypsum-rich clay. So the study compared ordinary cement with the lime-and-furnace-slag mixture across the properties that matter for pavement design, including strength, resistance to penetration, swelling, water absorption, and the material’s internal structure.
Here is the core idea. Think of loose soil particles as a pile of separate building blocks: a good treatment needs to make them grip one another and leave fewer open spaces between them. The treated clay with the lime-and-furnace-slag mixture formed a denser structure, while the cement-treated soil had more open spaces and more isolated clay plates.
Adding gypsum made the soil-and-binder phase more sealed. But strength is only half the story. When soaked, the lime-and-furnace-slag-treated soils expanded much more slowly and had a lower total volume change by the end of soaking. Even though strength-producing compounds formed alongside expanding crystals, the crystals’ tendency to expand in water was significantly reduced compared with the ordinary-cement-treated samples.
Water entering treated gypsum-rich ground can make it heave enough to threaten lightweight roads: one treatment reached about nineteen percent swelling, while the lime-based alternative stayed close to the ground’s original size even after soaking. The strength results point in the same direction.
After longer curing, the lime-and-furnace-slag-treated samples performed better than the ordinary-cement-treated samples, as stronger bonds formed over time. At seven days, the UCS of the lime-and-furnace-slag-treated samples performed better than that of the ordinary-cement-treated samples, showing the advantage was already present early in curing.
By twenty-eight days, the lime-and-furnace-slag-treated samples performed better than the ordinary-cement-treated samples, continuing the same strength advantage at the later curing period. Under soaked conditions, the four percent lime and eight percent GGBS treatment showed better performance, offering the most resistance against penetration overall.
The results also suggest that the best balance between gypsum and binder may exist at a particular mixture ratio, although that needs further investigation. Both treatments improved the compressive strength of gypsum-rich soil. But the lime-and-furnace-slag-treated soils showed higher strength than the ordinary-cement-treated samples at both curing stages and across every gypsum content tested.
The wet-condition result matters because ordinary cement showed more swelling than the lime-and-furnace-slag mixture. That makes the alternative mixture better suited to reducing sulphate-driven heave in soil beneath roads. In practical terms, the lime-and-furnace-slag combination enhanced the treated soil’s performance when soaked, even though the chemistry still produced some expanding minerals.
The paper’s final practical message is that the lime-and-furnace-slag mixture is a suitable alternative to ordinary cement for pavement construction, with the added advantage of a lower carbon footprint. For road construction over sulphate-rich ground, after twenty-eight days all lime-and-furnace-slag-treated samples exceeded CB1 strength requirements and proved suitable for CS, CB1, and CB2 applications.
Lime combined with a furnace by-product strengthened gypsum-rich clay more effectively than ordinary cement and reduced swelling in wet conditions. That could make road foundations more reliable where sulphate-rich ground is a problem.
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